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Zinc Oxide Nonmaterial Based Dye-Sensitized Solar Cells Using Natural Dyes Extracted from Different Plant Pigment

Received: 15 March 2022    Accepted: 19 April 2022    Published: 28 April 2022
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Abstract

Dye-sensitized solar cells (DSSCs) are a low-cost alternative to thin-film and silicon-based solar cells. Platinum is an effective catalytic material for creating DSSC counter electrodes (CEs), but it is also pricey. In this work, PEDOT was used as a counter electrode and ZnO was used as a photoanode. Natural dyes such as Fragaria x ananass, Amaranthus Iresine Herbstii, Bougainvillea spectacles and flowers, and Beta vulgaris (beetroot) were extracted with four solvents to fabricate dye-sensitized solar cells (DSSCs). The zinc oxide (ZnO) nanoparticles were successfully synthesized by simple sol-gel techniques. X-ray diffraction (XRD) confirms that the synthesized materials were in the hexagonal crystal structure. The crystallite sizes of the ZnO NPs were found to be 29 nm. The optical properties of ZnO and extracted natural dyes were studied using UV-visible spectroscopy. The conversion efficiency of DSSC extracted from distilled water using Beta vulgaris sensitizers was found to be 0.0328%, which is good compared to the other natural dyes. For all sensitizers, the effects of several parameters were analyzed, such as incident photon switching efficiency (IPCE), short-circuit density (Jsc), fill factor, and open-circuit voltage (Voc).

Published in American Journal of Modern Energy (Volume 8, Issue 2)
DOI 10.11648/j.ajme.20220802.11
Page(s) 18-24
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Dye-Sensitized Solar Cells, Natural Dye, Solvent, Electrolytes

References
[1] M-U. Rahman, M. Wei, F. Xie, M. Khan, “Efficient dye-sensitized solar cells composed of nanostructural ZnO doped with Ti” Catalysts., vol. 93, pp. 273, 2019.
[2] X. Zhou, Y. Xie, J. Ma, H. Mi, J. Yang, J. Cheng, T-K. Hoang, “Synthesis of hierarchical structure cuprous oxide by a novel two-step hydrothermal method and the effect of its addition on the photovoltaic properties of ZnO-based dye-sensitized solar cells”, J. Alloys Compd. vol 721, pp. 8-17, 2017.
[3] K. R. Aneesiya, C. Louis, “Localized surface plasmon resonance of Cu-doped ZnO nanostructures and the material’s integration in dye sensitized solar cells (DSSCs) enabling high open-circuit potentials” J. Alloys Compd, vol. 829, pp. 154497, 2020.
[4] K. A. Kumar, A. Pandurangan, S. Arumugam, M. Sathiskumar, “Effect of bi-functional hierarchical flower-like CoS nanostructure on its interfacial charge transport kinetics, magnetic and electrochemical behaviors for supercapacitor and DSSC applications” Sci. Rep, vol. 9, pp. 1–16, 2019.
[5] T-A. Geleta, T. Imae, “Influence of additives on zinc oxide-based dye sensitized solar cells” Bull. Chem. Soc. Jpn, vol. 93 (4), pp. 611-620, 2020.
[6] N-K. Hassan, M- R Hashim, Y. Al-Douri, “Morphology and optical investigations of ZnO pyramids and nanoflakes for optoelectronic applications” Optik, vol. 125 (11), pp. 2560-2564, 2014.
[7] S. Aksoy, O. Polat, K. Gorgun, Y. Caglar, M. Caglar, “Li doped ZnO based DSSC: Characterization and preparation of nanopowders and electrical performance of its DSSC” Physica E Low Dimens. Syst. Nanostruct, vol. 121, pp. 114127, 2020.
[8] M-A. Al-Alwani, N- A. Ludin, A- B. Mohamad, A- A- H. Kadhum, K. Sopian, “Extraction, preparation and application of pigments from Cordyline fruticosa and Hylocereus polyrhizus as sensitizers for dye-sensitized solar cells” Spectrochim. Acta A Mol. Biomol. Spectrosc, vol. 179, pp. 23-31, 2017.
[9] R-E. Adam, G. Pozina, M. Willander, O. Nur, “Synthesis of ZnO nanoparticles by co-precipitation method for solar driven photodegradation of Congo red dye at different pH” Photonics Nanostruct, vol. 32, pp. 11-18, 2018.
[10] P. Sanjay, K. Deepa, J. Madhavan, S. Senthil, “Optical, spectral and photovoltaic characterization of natural dyes extracted from leaves of Peltophorum pterocarpum and Acalypha amentacea used as sensitizers for ZnO based dye sensitized solar cells” Opt. Mater, vol. 83, pp. 192-199, 2018.
[11] M- I. Khan, M. Naeem, G- M. Mustafa, S-A. Abubshait, A. Mahmood, W. Al-Masry, S- M. Ramay, “Synthesis and characterization of Co and Ga co-doped ZnO thin films as an electrode for dye sensitized solar cells” Ceram. Vol. 46, no. 17, pp. 26590-26597, 2020.
[12] C. Mallikarjunaswamy, V- L. Ranganatha, R. Ramu, G. Nagaraju, “Facile microwave-assisted green synthesis of ZnO nanoparticles: application to photodegradation, antibacterial and antioxidant” J. Mater. Sci. Mater. Electron, vol. 31, no. 2, pp. 1004-1021, 2020.
[13] Q. Zhang, C. Li, TiO2 coated ZnO nanorods by mist chemical vapor deposition for application as photoanodes for dye-sensitized solar cells. Nanomater, vol. 9, no. 9, pp. 1339, 2019.
[14] H. Chang, H. M. Wu, T. L. Chen, K. D. Huang, C. S. Jwo, and Y. J. Lo, “Dye-sensitized solar cell using natural dyes extracted from spinach and ipomoea,” Journal of Alloys and Compounds, vol. 495, no. 2, pp. 606–610, 2010.
[15] N. M. Gómez-Ortíz, I. A. Vázquez-Maldonado, A. R. Pérez- Espadas, G. J. Mena-Rejón, J. A. Azamar-Barrios, and G. Oskam, “Dye-sensitized solar cells with natural dyes extracted from achiote seeds,” Sol. Energy Mater Sol. Cells, vol. 94, no. 1, pp. 40–44, 2010.
[16] S. Furukawa, H. Iino, T. Iwamoto, K. Kukita, and S. Yamauchi, “Characteristics of dye-sensitized solar cells using natural dye,” Thin Solid Films, vol. 518, no. 2, pp. 526–529, 2009.
[17] M-Ö. Karakuş, İ. Er. O. Koca, H. Çetin, “Dye ingredients and energy conversion efficiency at natural dye sensitized solar cells” Opt, vol. 66, pp. 552-558, 2017.
[18] R. Ramanarayanan, P. Nijisha, C-V. Niveditha, S. Sindhu, “Natural dyes from red amaranth leaves as light-harvesting pigments for dye-sensitized solar cells” Mater. Res. Bull. Vol. 90, pp 156-161, 2017.
[19] A. M. Ammar, H. S. Mohamed, M. M. Yousef, G. M. Abdel-Hafez, A. S. Hassanien, A. S. Khalil, “Dye-sensitized solar cells (DSSCs) based on extracted natural dyes” Nanomaterials. Vol. 2019.
[20] M. Hosseinnezhad, R. Jafari, K. Gharanjig, “Characterization of a green and environmentally friendly sensitizer for a low cost dye-sensitized solar cell” Opto-electron Rev, vol. 25, no. 2, pp. 93-98, 2017.
[21] W. J. E, Beek, M. M. Wienk. M. Kemerink, X. Yang, RAJ. Janssen, “Hybrid Zinc Oxide Conjugated Polymer Bulk Heterojunction Solar Cells” J. Phys. Chem. B, vol. 105, pp. 9505–951, 2005.
[22] L. Fan, S. Kang, J. Wu, S. Hao, Z. Lan, J. Lin, “Quasi-Solid State Dye-sensitized Solar Cells Based on Polyvinylpyrrolidone With Ionic Liquid”, J. Energy Sources A. Vol. 32, pp. 1559, 2010.
[23] A. Abdelkrim, S. Rahmane, O. Abdelouahab, N. Abdelmalek, G. Brahim, “Effect of solution concentration on the structural, optical and electrical properties of SnO2 thin films prepared by spray pyrolysis” Optik, vol. 127, pp. 2653–2658, 2016.
[24] N. S. Pesika, K. J. Stebe, P. C. Searson, “Determination of the particle size distribution of quantum nanocrystals from absorbance spectra” J. Adv. Mater, vo. 15, no. 15, pp. 1289-1291, 2003.
[25] N. T. R. N. Kumara, M. Petrović, D. S. U. Peiris, Y. A. Marie, C. Vijila, M. I. Petra, Ekanayake, P, “Efficiency enhancement of Ixora floral dye sensitized solar cell by diminishing the pigments interactions” Sol. Energy, vol. 117, pp. 36–45, 2015.
[26] T. M. El-Agez, A. A. El Tayyan, A. Al-Kahlout, S. A. Taya, M. S. Abdel-Latif, “Dye-sensitized solar cells based on ZnO films and natural dyes” J. Mater. Chem, vol. 2, no. 3, pp. 105-110, 2012.
[27] F. A. Unal, S. Ok, M. Unal, S. Topal, K. Cellat, F. Sen, “Synthesis, characterization, and application of transition metals (Ni, Zr, and Fe) doped TiO2 photoelectrodes for dye-sensitized solar cells”, J. Mol. Liq, vol. 299, pp. 112177, 2019.
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  • APA Style

    Wegene Lema Lachore. (2022). Zinc Oxide Nonmaterial Based Dye-Sensitized Solar Cells Using Natural Dyes Extracted from Different Plant Pigment. American Journal of Modern Energy, 8(2), 18-24. https://doi.org/10.11648/j.ajme.20220802.11

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    ACS Style

    Wegene Lema Lachore. Zinc Oxide Nonmaterial Based Dye-Sensitized Solar Cells Using Natural Dyes Extracted from Different Plant Pigment. Am. J. Mod. Energy 2022, 8(2), 18-24. doi: 10.11648/j.ajme.20220802.11

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    AMA Style

    Wegene Lema Lachore. Zinc Oxide Nonmaterial Based Dye-Sensitized Solar Cells Using Natural Dyes Extracted from Different Plant Pigment. Am J Mod Energy. 2022;8(2):18-24. doi: 10.11648/j.ajme.20220802.11

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  • @article{10.11648/j.ajme.20220802.11,
      author = {Wegene Lema Lachore},
      title = {Zinc Oxide Nonmaterial Based Dye-Sensitized Solar Cells Using Natural Dyes Extracted from Different Plant Pigment},
      journal = {American Journal of Modern Energy},
      volume = {8},
      number = {2},
      pages = {18-24},
      doi = {10.11648/j.ajme.20220802.11},
      url = {https://doi.org/10.11648/j.ajme.20220802.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajme.20220802.11},
      abstract = {Dye-sensitized solar cells (DSSCs) are a low-cost alternative to thin-film and silicon-based solar cells. Platinum is an effective catalytic material for creating DSSC counter electrodes (CEs), but it is also pricey. In this work, PEDOT was used as a counter electrode and ZnO was used as a photoanode. Natural dyes such as Fragaria x ananass, Amaranthus Iresine Herbstii, Bougainvillea spectacles and flowers, and Beta vulgaris (beetroot) were extracted with four solvents to fabricate dye-sensitized solar cells (DSSCs). The zinc oxide (ZnO) nanoparticles were successfully synthesized by simple sol-gel techniques. X-ray diffraction (XRD) confirms that the synthesized materials were in the hexagonal crystal structure. The crystallite sizes of the ZnO NPs were found to be 29 nm. The optical properties of ZnO and extracted natural dyes were studied using UV-visible spectroscopy. The conversion efficiency of DSSC extracted from distilled water using Beta vulgaris sensitizers was found to be 0.0328%, which is good compared to the other natural dyes. For all sensitizers, the effects of several parameters were analyzed, such as incident photon switching efficiency (IPCE), short-circuit density (Jsc), fill factor, and open-circuit voltage (Voc).},
     year = {2022}
    }
    

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  • TY  - JOUR
    T1  - Zinc Oxide Nonmaterial Based Dye-Sensitized Solar Cells Using Natural Dyes Extracted from Different Plant Pigment
    AU  - Wegene Lema Lachore
    Y1  - 2022/04/28
    PY  - 2022
    N1  - https://doi.org/10.11648/j.ajme.20220802.11
    DO  - 10.11648/j.ajme.20220802.11
    T2  - American Journal of Modern Energy
    JF  - American Journal of Modern Energy
    JO  - American Journal of Modern Energy
    SP  - 18
    EP  - 24
    PB  - Science Publishing Group
    SN  - 2575-3797
    UR  - https://doi.org/10.11648/j.ajme.20220802.11
    AB  - Dye-sensitized solar cells (DSSCs) are a low-cost alternative to thin-film and silicon-based solar cells. Platinum is an effective catalytic material for creating DSSC counter electrodes (CEs), but it is also pricey. In this work, PEDOT was used as a counter electrode and ZnO was used as a photoanode. Natural dyes such as Fragaria x ananass, Amaranthus Iresine Herbstii, Bougainvillea spectacles and flowers, and Beta vulgaris (beetroot) were extracted with four solvents to fabricate dye-sensitized solar cells (DSSCs). The zinc oxide (ZnO) nanoparticles were successfully synthesized by simple sol-gel techniques. X-ray diffraction (XRD) confirms that the synthesized materials were in the hexagonal crystal structure. The crystallite sizes of the ZnO NPs were found to be 29 nm. The optical properties of ZnO and extracted natural dyes were studied using UV-visible spectroscopy. The conversion efficiency of DSSC extracted from distilled water using Beta vulgaris sensitizers was found to be 0.0328%, which is good compared to the other natural dyes. For all sensitizers, the effects of several parameters were analyzed, such as incident photon switching efficiency (IPCE), short-circuit density (Jsc), fill factor, and open-circuit voltage (Voc).
    VL  - 8
    IS  - 2
    ER  - 

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Author Information
  • Faculty of Materials Science and Engineering, Jimma University, Jimma, Ethiopia

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